Yeah I figured that either there was some kind of file I could edit to manual do that kinda thing. Figured id ask.

I had an XP rig for video editing and had it set up as follows.
74GB Raptor Drive for OS and Apps
80GB for Windows XP Scratch Disk
160GB RAID 0 for Video Scratch Disk

I had the 80GB drive laying around and when I set it up for XP's scratch there was a slight performance gain in benchmarks. It was barely noticeable when running multiple apps while processing video.

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