Hello,
to 1.:
No OS can "Destroy" a HDD, in most cases
When u format a HDD to HFS u can simple delete the Partion and format it in NTFS or whatever u want.
So, should the OSX installation fails, u can boot from your Vista CD and install Vista, deleting your crap´t OSX. Just so simple
to 2.: I dont have a ATI, but i see kext for the 4600 HD card. So i would say Yes, it will work.
to 3.: Dont make it so complicate
Install Chamalion Bootloader, and u can boot from as many OS as u like.
I can recommend IdenebV1.4 10.5.6 a great and very Simple Distro. Or IPC 10.5.6
But for a beginner i think Ideneb is a bit easier.